The following code estimates the derivative of the function 
@math{f(x) = x^{3/2}} 
at @math{x=2} and at @math{x=0}.  The function @math{f(x)} is
undefined for @math{x<0} so the derivative at @math{x=0} is computed
using gsl_diff_forward.
#include <stdio.h>
#include <gsl/gsl_math.h>
#include <gsl/gsl_diff.h>
double f (double x, void * params)
{
  return pow (x, 1.5);
}
int
main (void)
{
  gsl_function F;
  double result, abserr;
  F.function = &f;
  F.params = 0;
  printf("f(x) = x^(3/2)\n");
  gsl_diff_central (&F, 2.0, &result, &abserr);
  printf("x = 2.0\n");
  printf("f'(x) = %.10f +/- %.5f\n", result, abserr);
  printf("exact = %.10f\n\n", 1.5 * sqrt(2.0));
  gsl_diff_forward (&F, 0.0, &result, &abserr);
  printf("x = 0.0\n");
  printf("f'(x) = %.10f +/- %.5f\n", result, abserr);
  printf("exact = %.10f\n", 0.0);
  return 0;
}
Here is the output of the program,
$ ./demo f(x) = x^(3/2) x = 2.0 f'(x) = 2.1213203435 +/- 0.01490 exact = 2.1213203436 x = 0.0 f'(x) = 0.0012172897 +/- 0.05028 exact = 0.0000000000